To understand why South Africa is the continent's biggest greenhouse gas emitter, look to the vast coal-fired power stations that dot the plains of Mpumalanga province.

Mpumalanga has eight coal plants within a 100 kilometer radius and recent research showed it was the world's second-biggest sulphur dioxide emissions hot spot. Environmentalists have documented thousands of cases of pollution-related illness.

But as Africa's No. 2 economy seeks to break its near-total coal dependence, climate experts say Mpumalanga could serve as a test case for developing nations seeking to cut emissions while also benefiting their people — a so-called just transition.